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  Set of Acidic Resin Catalysts To Correlate Structure and Reactivity in Fructose Conversion to 5-Hydroxymethylfurfural

Richter, F. H., Pupovac, K., Palkovits, R., & Schüth, F. (2013). Set of Acidic Resin Catalysts To Correlate Structure and Reactivity in Fructose Conversion to 5-Hydroxymethylfurfural. ACS Catalysis, 3(2), 123-127. doi:10.1021/cs3007439.

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 Creators:
Richter, Felix Herrmann1, Author              
Pupovac, Kristina2, Author              
Palkovits, Regina2, 3, Author              
Schüth, Ferdi1, Author              
Affiliations:
1Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, ou_1445589              
2Research Group Palkovits, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445615              
3Rhein Westfal TH Aachen, D-52056 Aachen, Germany, ou_persistent22              

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Free keywords: CATIONIC EXCHANGE RESINS; POLYMER NETWORKS; BIOMASS; DEHYDRATION; HYDROCARBONS; SULFONATION; CHEMICALS; XYLOSE; ACTIVATION; SYSTEM
 Abstract: A new synthetic route to acidic polystyrene-co-divinylbenzene resin catalysts allows systematic variation of cross-linker content, porosity, and acid site density. These resins are prepared in the form of powders by nanocasting, and the acid site density and the distribution of the acid sites in the prepared catalysts is controlled by liquid phase sulfonation with adjusted mixtures of sulfuric acid and oleum. This method allows identical synthesis conditions for the entire range of cross-linker content. With this set of model catalysts, the crosslinker content of the resin was found to be the most influential factor for the liquid phase dehydration of fructose to 5-hydroxymethylfurfural.

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Language(s): eng - English
 Dates: 2013-02-01
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: DOI: 10.1021/cs3007439
 Degree: -

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Title: ACS Catalysis
Source Genre: Journal
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Publ. Info: WASHINGTON, DC 20036 USA : AMER CHEMICAL SOC
Pages: - Volume / Issue: 3 (2) Sequence Number: - Start / End Page: 123 - 127 Identifier: ISSN: 2155-5435
CoNE: https://pure.mpg.de/cone/journals/resource/2155-5435