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  The Redox-Neutral Approach to C-H Functionalization

Peng, B., & Maulide, N. (2013). The Redox-Neutral Approach to C-H Functionalization. Chemistry-a European Journal, 19(40), 13274-13287. doi:10.1002/chem.201301522.

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 Creators:
Peng, Bo1, Author           
Maulide, Nuno1, Author           
Affiliations:
1Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445614              

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Free keywords: atom economy; C[BOND]H activation; C[BOND]H functionalization; hydride transfer; redox chemistry
 Abstract: The direct functionalization of C[BOND]H bonds is an attractive strategy in organic synthesis. Although several advances have been made in this area, the selective activation of inert sp3 C[BOND]H bonds remains a daunting challenge. Recently, a new type of sp3 C[BOND]H activation mode through internal hydride transfer has demonstrated the potential to activate remote sp3 C[BOND]H linkages in an atom-economic manner. This Minireview attempts to classify recent advances in this area including the transition to non-activated sp3 C[BOND]H bonds and asymmetric hydride transfers.

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Language(s): eng - English
 Dates: 2013-09-112013-09-27
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/chem.201301522
 Degree: -

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Title: Chemistry-a European Journal
  Other : Chem.-Eur. J.
Source Genre: Journal
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Publ. Info: -
Pages: - Volume / Issue: 19 (40) Sequence Number: - Start / End Page: 13274 - 13287 Identifier: ISSN: 0947-6539
CoNE: https://pure.mpg.de/cone/journals/resource/954926979058