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  Direct coupling of alcohols to form esters and amides with evolution of H2 using in situ formed ruthenium catalysts

Prechtl, M. H. G., Wobser, K., Theyssen, N., Ben-David, Y., Milstein, D., & Leitner, W. (2012). Direct coupling of alcohols to form esters and amides with evolution of H2 using in situ formed ruthenium catalysts. Catalysis Science & Technology, 2(12), 2039-2042. doi:10.1039/c2cy20429k.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0014-A2AE-2 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0019-FA71-6
Genre: Journal Article

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 Creators:
Prechtl, Martin H. G.1, 2, Author           
Wobser, Kathrin3, Author           
Theyssen, Nils4, Author           
Ben-David, Yehoshoa5, Author
Milstein, David5, Author
Leitner, Walter1, 2, Author           
Affiliations:
1Institut für Technische und Makromolekulare Chemie, Rheinisch-Westfälische Technische Hochschule Aachen, Worringer Weg 1, 52074 Aachen, Germany, ou_persistent22              
2Service Department Leitner (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, DE, ou_1445626              
3Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              
4Service Department Theyssen (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445632              
5Department of Organic Chemistry, The Weizmann Institute of Science, Rehovot, 76100, Israel, ou_persistent22              

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 Abstract: A simple approach for the catalytic conversion of primary alcohols into their corresponding esters and amides, with evolution of H2 gas using in situ formed ruthenium PNP- and PNN-pincer catalysts, is presented. The evaluation showed conversions for the esterification with turnover numbers as high as 4300, and 4400 for the amidation.

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Language(s): eng - English
 Dates: 2012-06-222912-07-082012-07-102012-11-06
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/c2cy20429k
 Degree: -

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Title: Catalysis Science & Technology
  Other : Catal. Sci. Technol.
Source Genre: Journal
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Publ. Info: Cambridge : Royal Society of Chemistry
Pages: 4 Volume / Issue: 2 (12) Sequence Number: - Start / End Page: 2039 - 2042 Identifier: Other: 2044-4753
CoNE: https://pure.mpg.de/cone/journals/resource/2044-4753