English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
 
 
DownloadE-Mail
 Local TagsRelease HistoryDetailsSummary
  Versatile Access to Chiral Indolines by Catalytic Asymmetric Fischer Indolization

Martínez, A., Webber, M. J., Müller, S., & List, B. (2013). Versatile Access to Chiral Indolines by Catalytic Asymmetric Fischer Indolization. Angewandte Chemie International Edition, 52(36), 9486-9490. doi:10.1002/anie.201301618.

Item is

 

show all hide all

Basic

show hide
Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0014-C9F6-4 Version Permalink: https://hdl.handle.net/21.11116/0000-0008-4C4F-C
Genre: Journal Article

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Martínez, Alberto1, Author           
Webber, Matthew J.1, Author           
Müller, Steffen1, Author           
List, Benjamin1, Author           
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, ou_1445585              

Content

show
hide
Free keywords: Brønsted acid catalysis; Fischer indole synthesis; heterocycles; indoline; organocatalysis
 Abstract: “Fisching” for complexity: The chiral Brønsted acid (R)‐STRIP catalyzes the asymmetric Fischer indolization of a range of monosubstituted cyclopentanones and cyclohexanones to give chiral fused indolines bearing a quaternary stereogenic center at the 3‐position. The method has been extended to include substrates bearing a tethered nucleophile, thus allowing for enantioselective indolization/ring‐closing cascades to complex propellanes featuring two vicinal quaternary stereocenters.

Details

show
hide
Language(s): eng - English
 Dates: 2013-02-252013-04-292013-09-02
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201301618
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 52 (36) Sequence Number: - Start / End Page: 9486 - 9490 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851