English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Organotextile Catalysis

Lee, J.-W., Mayer-Gall, T., Opwis, K., Song, C. E., Gutmann, J. S., & List, B. (2013). Organotextile Catalysis. Science, 341(6151), 1225-1229. doi:10.1126/science.1242196.

Item is

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Lee, Ji-Woong1, Author              
Mayer-Gall, Thomas2, Author
Opwis, Klaus2, Author
Song, Choong Eui3, Author
Gutmann, Jochen Stefann2, 4, Author
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, ou_1445585              
2Deutsches Textilforschungszentrum Nord-West gGmbH, Adlerstraße 1, 47798 Krefeld, Germany, ou_persistent22              
3Department of Chemistry, Sungkyunkwan University, 300 Cheoncheon, Jangan, Suwon, Gyeonggi, 440-746, Korea, ou_persistent22              
4Institute of Physical Chemistry and CENIDE (Center for Nanointegration), University Duisburg-Essen, Universitätsstraße 5, 45117 Essen, Germany, ou_persistent22              

Content

show
hide
Free keywords: -
 Abstract: Throughout human history, textiles have been integral to daily life, but their exploration in catalysis has been rare. Herein, we show a facile and permanent immobilization of organocatalysts on the textile nylon using ultraviolet light. The catalyst and the textile material require no chemical modification for the immobilization. All of the prepared textile-immobilized organocatalysts (a Lewis basic, a Brønsted acidic, and a chiral organocatalyst) display excellent stability, activity, and recyclability for various organic transformations. Very good enantioselectivity (>95:5 enantiomeric ratio) can be maintained for more than 250 cycles of asymmetric catalysis. Practical and straightforward applications of textile organocatalysis may be beneficial for various fields by offering inexpensive and accessible functionalized catalytic materials.

Details

show
hide
Language(s): eng - English
 Dates: 2013-09-13
 Publication Status: Published in print
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1126/science.1242196
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Science
  Abbreviation : Science
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Washington, D.C. : American Association for the Advancement of Science
Pages: - Volume / Issue: 341 (6151) Sequence Number: - Start / End Page: 1225 - 1229 Identifier: ISSN: 0036-8075
CoNE: https://pure.mpg.de/cone/journals/resource/991042748276600_1