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  An Orders-of-Magnitude Increase in the Rate of the Solid-Catalyzed CO Oxidation by In Situ Ball Milling

Immohr, S., Felderhoff, M., Weidenthaler, C., & Schüth, F. (2013). An Orders-of-Magnitude Increase in the Rate of the Solid-Catalyzed CO Oxidation by In Situ Ball Milling. Angewandte Chemie International Edition, 52(48), 12688-12691. doi:10.1002/anie.201305992.

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 Creators:
Immohr, Sarah1, Author              
Felderhoff, Michael1, Author              
Weidenthaler, Claudia2, Author              
Schüth, Ferdi1, Author              
Affiliations:
1Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445589              
2Research Group Weidenthaler, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1950291              

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Free keywords: ball milling; chromium; heterogeneous catalysis; oxidation; solvent-free reactions
 Abstract: Shaken, not stirred: CO oxidation was carried out continuously in a shaker ball mill. During milling, the reaction rate increases dramatically, but drops rapidly to zero when the mill is stopped. Compared to a conventional experiment in a plug‐flow reactor, the rate of a ball‐mill reaction catalyzed by Cr2O3 is three orders of magnitude higher at room temperature and one order of magnitude higher at 100°C.

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Language(s): eng - English
 Dates: 2013-07-102013-09-232013-11-25
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201305992
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 52 (48) Sequence Number: - Start / End Page: 12688 - 12691 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851