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  Second-Generation Total Synthesis of Spirastrellolide F Methyl Ester: The Alkyne Route

Benson, S., Collin, M.-P., Arlt, A., Gabor, B., Goddard, R., & Fürstner, A. (2011). Second-Generation Total Synthesis of Spirastrellolide F Methyl Ester: The Alkyne Route. Angewandte Chemie International Edition, 50(37), 8739-8744. doi:10.1002/anie.201103270.

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anie_201103270_sm_miscellaneous_information.pdf (Supplementary material), 3MB
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anie_201103270_sm_miscellaneous_information.pdf
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Supporting Information
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application/pdf / [MD5]
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Copyright Date:
2011
Copyright Info:
Wiley-VCH 69451 Weinheim, Germany
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 Creators:
Benson, Stefan1, Author              
Collin, Marie-Pierre1, Author              
Arlt, Alexander1, Author              
Gabor, Barbara2, Author              
Goddard, Richard3, Author              
Fürstner, Alois1, Author              
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              
2Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445623              
3Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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Free keywords: alkyne metathesis; gold; molybdenum; natural products; total synthesis
 Abstract: Outlandish: The spiroketal embedded in spirastrellolide F methyl ester is a daring site for ring closure, yet it has allowed the power of catalytic alkyne scission and activation to be showcased. An improved strategy for the introduction of the labile side chain was also developed.

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Language(s): eng - English
 Dates: 2012-05-122011-07-262011-09-05
 Publication Status: Published in print
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201103270
 Degree: -

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Title: Angewandte Chemie International Edition
  Other : Angewandte Chemie - International Edition
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH Verlag GmbH & Co. KGaA
Pages: - Volume / Issue: 50 (37) Sequence Number: - Start / End Page: 8739 - 8744 Identifier: CoNE: https://pure.mpg.de/cone/journals/resource/201310171