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  Second-Generation Total Synthesis of Spirastrellolide F Methyl Ester: The Alkyne Route

Benson, S., Collin, M.-P., Arlt, A., Gabor, B., Goddard, R., & Fürstner, A. (2011). Second-Generation Total Synthesis of Spirastrellolide F Methyl Ester: The Alkyne Route. Angewandte Chemie International Edition, 50(37), 8739-8744. doi:10.1002/anie.201103270.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0014-CA40-1 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0014-CA41-0
Genre: Journal Article

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anie_201103270_sm_miscellaneous_information.pdf (Supplementary material), 3MB
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https://hdl.handle.net/11858/00-001M-0000-0014-CA42-E
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anie_201103270_sm_miscellaneous_information.pdf
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Supporting Information
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Copyright Date:
2011
Copyright Info:
Wiley-VCH 69451 Weinheim, Germany
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 Creators:
Benson, Stefan1, Author           
Collin, Marie-Pierre1, Author           
Arlt, Alexander1, Author           
Gabor, Barbara2, Author           
Goddard, Richard3, Author           
Fürstner, Alois1, Author           
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              
2Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445623              
3Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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Free keywords: alkyne metathesis; gold; molybdenum; natural products; total synthesis
 Abstract: Outlandish: The spiroketal embedded in spirastrellolide F methyl ester is a daring site for ring closure, yet it has allowed the power of catalytic alkyne scission and activation to be showcased. An improved strategy for the introduction of the labile side chain was also developed.

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Language(s): eng - English
 Dates: 2012-05-122011-07-262011-09-05
 Publication Status: Issued
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201103270
 Degree: -

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Title: Angewandte Chemie International Edition
  Other : Angewandte Chemie - International Edition
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH Verlag GmbH & Co. KGaA
Pages: - Volume / Issue: 50 (37) Sequence Number: - Start / End Page: 8739 - 8744 Identifier: CoNE: https://pure.mpg.de/cone/journals/resource/201310171