English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Negative linear compression and expanding NH N bonds in an imidazoline compound.

Aniola, M., Katrusiak, A., & Kia, R. (2012). Negative linear compression and expanding NH N bonds in an imidazoline compound. CrystEngComm, 14(20), 6424-6427. doi:10.1039/C2CE25507C.

Item is

Basic

show hide
Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0014-A98F-E Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0027-CB88-D
Genre: Journal Article

Files

show Files
hide Files
:
1855092.pdf (Publisher version), 573KB
 
File Permalink:
-
Name:
1855092.pdf
Description:
-
Visibility:
Restricted (Max Planck Institute for Biophysical Chemistry (Karl Friedrich Bonhoeffer Institute), Göttingen; )
MIME-Type / Checksum:
application/pdf
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-
:
1855092_Suppl_1.pdf (Supplementary material), 602KB
Name:
1855092_Suppl_1.pdf
Description:
-
Visibility:
Public
MIME-Type / Checksum:
application/pdf / [MD5]
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-
:
1855092_Suppl_2.txt (Supplementary material), 32KB
Name:
1855092_Suppl_2.txt
Description:
-
Visibility:
Public
MIME-Type / Checksum:
text/plain / [MD5]
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-

Locators

show
hide
Description:
-

Creators

show
hide
 Creators:
Aniola, M., Author
Katrusiak, A., Author
Kia, R.1, Author              
Affiliations:
1Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society, ou_578564              

Content

show
hide
Free keywords: -
 Abstract: The 3-dimensional network of NHN hydrogen bonds and ClCl hydrogen contacts in the crystal structure of 2-(3′-chlorophenyl)imidazoline exhibits an anomalous hydrostatic compression. The lengthening of hydrogen bonds NHN and some CHN contacts as well as their supramolecular architecture lead to anomalous expansion of the crystal along [x] and [y] on increasing pressure to 0.1 GPa. The mechanism of this phenomenon is due to the ‘stiffness’ of the NHN and ClCl interactions and ‘softness’ of other van der Waals contacts. Above 0.1 GPa all crystal directions become compressed. However, up to 1.20 GPa, the crystal remains in the same orthorhombic phase of polar space group Fdd2.

Details

show
hide
Language(s): eng - English
 Dates: 2012-07-062012
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: Peer
 Identifiers: DOI: 10.1039/C2CE25507C
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: CrystEngComm
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: -
Pages: - Volume / Issue: 14 (20) Sequence Number: - Start / End Page: 6424 - 6427 Identifier: -