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  Direct Domino Synthesis of Azido-Dienoic Acids: Potential Linker Units

Souris, C., Frébault, F., Audisio, D., Farès, C., & Maulide, N. (2013). Direct Domino Synthesis of Azido-Dienoic Acids: Potential Linker Units. Synlett, 24(10), 1286-1290. doi:10.1055/s-0033-1338452.

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sup_st-2013-d0143-l_10-1055_s-0033-1338452.pdf (Supplementary material), 3MB
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sup_st-2013-d0143-l_10-1055_s-0033-1338452.pdf
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Supporting Information
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Copyright Date:
2013
Copyright Info:
Georg Thieme Verlag KG Stuttgart · New York
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 Creators:
Souris, Caroline1, Author           
Frébault, Frédéric1, Author           
Audisio, Davide1, Author           
Farès, Christophe2, Author           
Maulide, Nuno1, Author           
Affiliations:
1Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445614              
2Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445623              

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Free keywords: azide; dienes; electrocyclic; allylic alkylation; bio­conjugation
 Abstract: We report an atom-economical domino synthesis of functionalized and stereodefined dienes. This method hinges on an allylic alkylation–electrocyclic ring-opening sequence and allows direct access to doubly vinylogous azido-dienoic acids bearing challenging substitution patterns. This class of compounds re­presents useful linkers in chemical biology by virtue of the ortho­gonality between the azido and carboxylic acid moieties.

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Language(s): eng - English
 Dates: 2013-02-132013-04-052013-05-082013-06-16
 Publication Status: Published in print
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1055/s-0033-1338452
 Degree: -

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Title: Synlett
  Other : Synlett
Source Genre: Journal
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Publ. Info: Stuttgart : Georg Thieme Verlag
Pages: - Volume / Issue: 24 (10) Sequence Number: - Start / End Page: 1286 - 1290 Identifier: ISSN: 0936-5214
CoNE: https://pure.mpg.de/cone/journals/resource/954925570856