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  Biogenic metal–organic frameworks: 2,5-Furandicarboxylic acid as versatile building block

Rose, M., Weber, D., Lotsch, B. V., Kremer, R. K., Goddard, R., & Palkovits, R. (2013). Biogenic metal–organic frameworks: 2,5-Furandicarboxylic acid as versatile building block. Microporous and Mesoporous Materials, 181, 217-221. doi:10.1016/j.micromeso.2013.06.039.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0014-CA06-7 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0014-CA07-5
Genre: Journal Article

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mmc1.pdf (Supplementary material), 655KB
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 Creators:
Rose, Marcus1, Author
Weber, Daniel2, 3, Author
Lotsch, Bettina V.2, 3, Author
Kremer, Reinhard K.2, Author
Goddard, Richard4, Author              
Palkovits, Regina1, Author
Affiliations:
1Institut für Technische und Makromolekulare Chemie, RWTH Aachen University, Worringerweg 1, Aachen, Germany, ou_persistent22              
2Max Planck Institute for Solid State Research, Heisenbergstraße 1, 70569 Stuttgart, Germany, ou_persistent22              
3LMU München, Butenandtstraße 5-13, 81377 München, Germany, ou_persistent22              
4Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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Free keywords: Metal–organic framework; Porous; Furandicarboxylic acid; Biomass; Building block
 Abstract: 2,5-Furandicarboxylic acid (FDA) is a promising renewable building block. It can be derived from cellulosic biomass and therefore poses no competition to the food chain. FDA is considered a valuable replacement for terephthalic acid in the industrial production of poly(ethylene terephthalate). Thus, the biogenic linker was investigated in the formation of metal–organic frameworks (MOFs). Novel crystalline compounds and gels have been synthesized and extensively characterized. The bi-functional linker forms Cu-, Al- and Fe-containing framework materials with hierarchical pore systems and high surface areas. Depending on the synthesis conditions crystalline Cu MOFs have been obtained exhibiting dense packings as well as open microporosity. In contrast, Al and Fe resulted in three-dimensional amorphous metal–organic framework gels with hierarchical pore systems ranging from micro- and meso-up to small macropores. By varying the metal connector as well as synthesis conditions the adsorption properties regarding the pore size and specific surface area can thus be tailored utilizing the versatile biogenic linker FDA that can be produced from renewable resources.

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Language(s): eng - English
 Dates: 2013-05-222012-12-032013-06-282013-07-102013-11-15
 Publication Status: Published in print
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Method: Peer
 Identifiers: DOI: 10.1016/j.micromeso.2013.06.039
 Degree: -

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Title: Microporous and Mesoporous Materials
Source Genre: Journal
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Publ. Info: Amsterdam : Elsevier
Pages: 5 Volume / Issue: 181 Sequence Number: - Start / End Page: 217 - 221 Identifier: ISSN: 1387-1811
CoNE: /journals/resource/954926228401