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  Biogenic metal–organic frameworks: 2,5-Furandicarboxylic acid as versatile building block

Rose, M., Weber, D., Lotsch, B. V., Kremer, R. K., Goddard, R., & Palkovits, R. (2013). Biogenic metal–organic frameworks: 2,5-Furandicarboxylic acid as versatile building block. Microporous and Mesoporous Materials, 181, 217-221. doi:10.1016/j.micromeso.2013.06.039.

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Datensatz-Permalink: http://hdl.handle.net/11858/00-001M-0000-0014-CA06-7 Versions-Permalink: http://hdl.handle.net/11858/00-001M-0000-0014-CA07-5
Genre: Zeitschriftenartikel

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mmc1.pdf (Ergänzendes Material), 655KB
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 Urheber:
Rose, Marcus1, Autor
Weber, Daniel2, 3, Autor
Lotsch, Bettina V.2, 3, Autor
Kremer, Reinhard K.2, Autor
Goddard, Richard4, Autor              
Palkovits, Regina1, Autor
Affiliations:
1Institut für Technische und Makromolekulare Chemie, RWTH Aachen University, Worringerweg 1, Aachen, Germany, ou_persistent22              
2Max Planck Institute for Solid State Research, Heisenbergstraße 1, 70569 Stuttgart, Germany, ou_persistent22              
3LMU München, Butenandtstraße 5-13, 81377 München, Germany, ou_persistent22              
4Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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Schlagwörter: Metal–organic framework; Porous; Furandicarboxylic acid; Biomass; Building block
 Zusammenfassung: 2,5-Furandicarboxylic acid (FDA) is a promising renewable building block. It can be derived from cellulosic biomass and therefore poses no competition to the food chain. FDA is considered a valuable replacement for terephthalic acid in the industrial production of poly(ethylene terephthalate). Thus, the biogenic linker was investigated in the formation of metal–organic frameworks (MOFs). Novel crystalline compounds and gels have been synthesized and extensively characterized. The bi-functional linker forms Cu-, Al- and Fe-containing framework materials with hierarchical pore systems and high surface areas. Depending on the synthesis conditions crystalline Cu MOFs have been obtained exhibiting dense packings as well as open microporosity. In contrast, Al and Fe resulted in three-dimensional amorphous metal–organic framework gels with hierarchical pore systems ranging from micro- and meso-up to small macropores. By varying the metal connector as well as synthesis conditions the adsorption properties regarding the pore size and specific surface area can thus be tailored utilizing the versatile biogenic linker FDA that can be produced from renewable resources.

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Sprache(n): eng - Englisch
 Datum: 2013-05-222012-12-032013-06-282013-07-102013-11-15
 Publikationsstatus: Im Druck veröffentlicht
 Seiten: 5
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: Expertenbegutachtung
 Identifikatoren: DOI: 10.1016/j.micromeso.2013.06.039
 Art des Abschluß: -

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Quelle 1

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Titel: Microporous and Mesoporous Materials
Genre der Quelle: Zeitschrift
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Ort, Verlag, Ausgabe: Amsterdam : Elsevier
Seiten: 5 Band / Heft: 181 Artikelnummer: - Start- / Endseite: 217 - 221 Identifikator: ISSN: 1387-1811
CoNE: /journals/resource/954926228401