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  Unveiling Photodeactivation Pathways for a New Iridium(III) Cyclometalated Complex

Escudero, D., Heuser, E., Meier, R. J., Schäferling, M., Thiel, W., & Holder, E. (2013). Unveiling Photodeactivation Pathways for a New Iridium(III) Cyclometalated Complex. Chemistry - A European Journal, 19(46), 15639-15644. doi:10.1002/chem.201301291.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0014-C99B-0 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0014-C99C-E
Genre: Journal Article

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chem_201301291_sm_miscellaneous_information.pdf (Supplementary material), 632KB
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chem_201301291_sm_miscellaneous_information.pdf
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Supporting Information
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Copyright Date:
2013
Copyright Info:
Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim
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 Creators:
Escudero, Daniel1, Author              
Heuser, Eike2, 3, Author
Meier, Robert J.4, Author
Schäferling, Michael5, Author
Thiel, Walter1, Author              
Holder, Elisabeth2, 3, Author
Affiliations:
1Research Department Thiel, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445590              
2Functional Polymers Group and Institute of Polymer Technology University of Wuppertal, Gaußstrasse 20, 42097 Wuppertal (Germany), ou_persistent22              
3Dutch Polymer Institute (DPI), P. O. Box 513, 5600 AX Eindhoven (The Netherlands), ou_persistent22              
4Institute of Analytical Chemistry, Chemo- and Biosensors University of Regensburg, 93040 Regensburg (Germany), ou_persistent22              
5Department of Biochemistry/Biotechnology, University of Turku, Tykistçkatu 6A, BioCity 6th floor, 20520 Turku (Finland), ou_persistent22              

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Free keywords: density functional calculations; iridium; non-adiabatic phenomena; photochemistry; photophysics
 Abstract: We report the synthesis and characterization of a neutral heteroleptic IrIII complex bearing 6-fluoro-2-phenylbenzo[d]thiazole as cyclometalating ligand and (Z)-6-(9H-carbazol-9-yl)-5-hydroxy-2,2-dimethylhex-4-en-3-one as ancillary ligand. The photodeactivation mechanisms have been elucidated through extensive density functional theory (DFT) calculations. The active role of metal-centered (3MC) triplet excited states in the nonradiative deactivation pathways is, for first time, confirmed in such complexes.

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Language(s): eng - English
 Dates: 2013-08-062013-04-052013-10-022013-11-11
 Publication Status: Published in print
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/chem.201301291
 Degree: -

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Title: Chemistry - A European Journal
  Other : Chem. Eur. J.
Source Genre: Journal
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Publ. Info: Weinheim, Germany : VCH Verlagsgesellschaft
Pages: 6 Volume / Issue: 19 (46) Sequence Number: - Start / End Page: 15639 - 15644 Identifier: ISSN: 0947-6539
CoNE: https://pure.mpg.de/cone/journals/resource/954926979058