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  Photoinduced Gold(I)–Gold(I) Chemical Bonding in Dicyanoaurate Oligomers

Cui, G., Cao, X.-Y., Fang, W.-H., Dolg, M., & Thiel, W. (2013). Photoinduced Gold(I)–Gold(I) Chemical Bonding in Dicyanoaurate Oligomers. Angewandte Chemie International Edition, 52(39), 10281-10285. doi:10.1002/anie.201305487.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0014-C93E-2 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0014-C93F-F
Genre: Journal Article

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anie_201305487_sm_miscellaneous_information.pdf (Supplementary material), 2MB
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anie_201305487_sm_miscellaneous_information.pdf
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Supporting Information
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application/pdf / [MD5]
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Copyright Date:
2013
Copyright Info:
Wiley-VCH 69451 Weinheim, Germany
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 Creators:
Cui, Ganglong1, 2, Author              
Cao, Xiao-Yan3, Author
Fang, Wei-Hai2, Author
Dolg, Michael3, Author
Thiel, Walter1, Author              
Affiliations:
1Research Department Thiel, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445590              
2Chemistry College, Beijing Normal University, Beijing 100875 (China), ou_persistent22              
3Institut für Theoretische Chemie, Universität zu Köln, Greinstr. 4, 50939 Köln (Germany), ou_persistent22              

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Free keywords: Au–Au bonds; aurophilicity; electronic structure; excited states; photochemistry
 Abstract: Not only σ*σ but also σ*π: High-level electronic structure calculations reveal the σ*σ and σ*π bonding patterns for AuI–AuI bonding in excited states and suggest two conformation-dependent photophysical relaxation mechanisms for dicyanoaurate oligomers (n=2–5; see picture) in aqueous solution. These insights into the excited-state electronic structure should also be relevant for other gold complexes with a similar gold scaffold.

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Language(s): eng - English
 Dates: 2013-06-262013-08-122013-09-23
 Publication Status: Published in print
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201305487
 Degree: -

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Title: Angewandte Chemie International Edition
  Other : Angewandte Chemie - International Edition
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH Verlag GmbH & Co. KGaA
Pages: 5 Volume / Issue: 52 (39) Sequence Number: - Start / End Page: 10281 - 10285 Identifier: CoNE: https://pure.mpg.de/cone/journals/resource/201310171