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  Catena-Poly[{[mu]3-4,4',6,6'-tetrabromo-2,2'-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}{[mu]2-4,4',6,6'-tetrabromo-2,2'-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}dicopper(II)].

Kargar, H., Kia, R., Adabi Ardakani, A., & Tahir, M. N. (2012). Catena-Poly[{[mu]3-4,4',6,6'-tetrabromo-2,2'-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}{[mu]2-4,4',6,6'-tetrabromo-2,2'-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}dicopper(II)]. Acta Crystallographica E, 68(7): m1018-m1019. doi:10.1107/S1600536812029285.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0014-B664-3 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-002C-1FB9-D
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http://journals.iucr.org/e/issues/2012/07/00/rz2776/rz2776.pdf (Publisher version)
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Kargar, H., Author
Kia, R.1, Author           
Adabi Ardakani, A., Author
Tahir, M. N., Author
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1Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society, ou_578564              

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 Abstract: The asymmetric unit of the title coordination polymer consists of a dinuclear neutral complex molecule of formula [Cu2(C18H14Br4N2O2)2]n. One of the CuII ions is coordinated in a distorted square-planar geometry, whereas the other is coordinated in a distorted square-pyramidal geometry, the long apical Cu-O bond [2.885 (4) Å] of the square-pyramidal coordination being provided by a symmetry-related O atom creating a one-dimensional polymer along [010]. [pi]-[pi] stacking interactions [centroid-centroid distance = 3.783 (4) Å] and short interchain Br...Br interactions [3.6142 (12)-3.6797 (12) Å] are observed.

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Language(s): eng - English
 Dates: 2012-07
 Publication Status: Published online
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 Rev. Type: Peer
 Identifiers: DOI: 10.1107/S1600536812029285
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Title: Acta Crystallographica E
Source Genre: Journal
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Pages: - Volume / Issue: 68 (7) Sequence Number: m1018-m1019 Start / End Page: - Identifier: -