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  {4,4',6,6'-Tetraiodo-2,2'-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}nickel(II).

Kargar, H., Kia, R., Shakarami, T., & Tahir, M. N. (2012). {4,4',6,6'-Tetraiodo-2,2'-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}nickel(II). Acta Crystallographica E, 68(7): m935. doi:10.1107/S1600536812024944.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0014-B67E-B Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0027-CF44-3
Genre: Journal Article

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 Creators:
Kargar, H., Author
Kia, R.1, Author              
Shakarami, T., Author
Tahir, M. N., Author
Affiliations:
1Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society, ou_578564              

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 Abstract: The asymmetric unit of the title compound, [Ni(C19H16I4N2O2)], comprises half of a Schiff base complex. The NiII atom is located on a twofold rotation axis which also bisects the central C atom of the 2,2-dimethylpropane group of the ligand. The geometry around the NiII atom is distorted square-planar, with a dihedral angle of 21.7 (3)° between the symmetry-related N/Ni/O coordination planes. The dihedral angle between the symmetry-related benzene rings is 27.9 (3)°. In the crystal, short intermolecular I...I [3.8178 (9) and 3.9013 (10) Å] interactions are present.

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Language(s): eng - English
 Dates: 2012-07
 Publication Status: Published online
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 Rev. Method: Peer
 Identifiers: DOI: 10.1107/S1600536812024944
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Title: Acta Crystallographica E
Source Genre: Journal
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Pages: - Volume / Issue: 68 (7) Sequence Number: m935 Start / End Page: - Identifier: -