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  Catena-Poly[{[mu]3-4,4',6,6'-tetrachloro-2,2'-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}{[mu]2-4,4',6,6'-tetrachloro-2,2'-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}dicopper(II)].

Kia, R., Kargar, H., Adabi Ardakani, A., & Tahir, M. N. (2012). Catena-Poly[{[mu]3-4,4',6,6'-tetrachloro-2,2'-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}{[mu]2-4,4',6,6'-tetrachloro-2,2'-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolato}dicopper(II)]. Acta Crystallographica E, 68(7), m999-m1000. doi:10.1107/S1600536812028462.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0014-B85E-3 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002C-1FB4-8
Genre: Journal Article

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Kia, R.1, Author              
Kargar, H., Author
Adabi Ardakani, A., Author
Tahir, M. N., Author
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1Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society, ou_578564              

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 Abstract: The asymmetric unit of the title compound, [Cu2(C18H14Cl4N2O2)2]n, contains two independent CuII ions which are bridged by a pair of 4,4',6,6'-tetrachloro-2,2'-[butane-1,4-diylbis(nitrilomethanylylidene)]diphenolate ligands, forming a dinuclear unit. One of the CuII ions is coordinated in a distorted square-planar environment and the other is coordinated in a distorted square-pyramidal environment. The long apical Cu-O bond of the square-pyramidal coordinated CuII ion is formed by a symmetry-related O atom, creating a one-dimensional polymer along [010]. In addition, short intermolecular Cl...Cl distances [3.444 (2) Å] and weak [pi]-[pi] interactions [centroid-centroid distances = 3.736 (2)-3.875 (3) Å] are observed. The crystal studied was an inversion twin with a refined twin component ratio of 0.60 (1):0.40 (1).

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Language(s): eng - English
 Dates: 2012-07
 Publication Status: Published online
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 Rev. Method: Peer
 Identifiers: DOI: 10.1107/S1600536812028462
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Title: Acta Crystallographica E
Source Genre: Journal
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Pages: - Volume / Issue: 68 (7) Sequence Number: - Start / End Page: m999 - m1000 Identifier: -