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  Reversible stabilization of transition-metal-binding DNA G-quadruplexes.

Engelhard, D. M., Pievo, R., & Clever, G. H. (2013). Reversible stabilization of transition-metal-binding DNA G-quadruplexes. Angewandte Chemie-International Edition, 52(49), 12843-12847. doi:10.1002/anie.201307594.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0014-C680-4 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0027-CBA4-D
Genre: Journal Article

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1868176.pdf (Publisher version), 984KB
 
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 Creators:
Engelhard, D. M., Author
Pievo, R.1, Author              
Clever, G. H., Author
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1Research Group of Electron Paramagnetic Resonance, MPI for Biophysical Chemistry, Max Planck Society, ou_578606              

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 Abstract: You can't top the CopperTop: Tetramolecular G-quadruplexes modified with terminal pyridine ligands exhibit metal-triggered stabilization as monitored by thermal denaturation studies, circular dichroism, and nondenaturing gel electrophoresis. Formation of the square-planar CuII(pyridine)4 complex was confirmed by EPR measurements. The metal complexation is fully reversible by removal of the transition metal with ethylenediaminetetraacetic acid (edta).

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Language(s): eng - English
 Dates: 2013-11-072013-12-02
 Publication Status: Published in print
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 Rev. Method: Peer
 Identifiers: DOI: 10.1002/anie.201307594
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Title: Angewandte Chemie-International Edition
Source Genre: Journal
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Pages: - Volume / Issue: 52 (49) Sequence Number: - Start / End Page: 12843 - 12847 Identifier: -