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  The Catalytic Asymmetric α-Benzylation of Aldehydes

List, B., Čorić, I., Grygorenco, O. O., Kaib, P. S. J., Komarov, I., Lee, A., et al. (2014). The Catalytic Asymmetric α-Benzylation of Aldehydes. Angewandte Chemie International Edition, 53(1), 282-285. doi:10.1002/anie.201306037.

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 Creators:
List, Benjamin1, Author              
Čorić, Ilija1, Author              
Grygorenco, Oleksandr O.2, Author
Kaib, Philip S. J.1, Author              
Komarov, Igor2, Author
Lee, Anna1, Author              
Leutzsch, Markus1, Author              
Pan, Subhas Chandra1, Author              
Tymtsunik, Andrey V.2, Author
van Gemmeren, Manuel1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              
2Taras Shevchenko National University of Kyiv, Volodymyrska Street 60, Kyiv (Ukraine), ou_persistent22              

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Free keywords: α-alkylation; α-branched aldehydes; DYKATt; enamine catalysis; organocatalysis
 Abstract: The first aminocatalyzed α-alkylation of α-branched aldehydes with benzyl bromides as alkylating agents has been developed. Using a sterically demanding proline derived catalyst, racemic α-branched aldehydes are reacted with alkylating agents in a DYKAT process to give the corresponding α-alkylated aldehydes with quaternary stereogenic centers in good yields and high enantioselectivities.

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Language(s): eng - English
 Dates: 2013-07-112013-11-242014-01-03
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201306037
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 53 (1) Sequence Number: - Start / End Page: 282 - 285 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851