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  Extreme Biomimetics: formation of zirconium dioxide nanophase using chitinous scaffolds under hydrothermal conditions

Ehrlich, H., Simon, P., Motylenko, M., Wysokowski, M., Bazhenov, V. V., Galli, R., et al. (2013). Extreme Biomimetics: formation of zirconium dioxide nanophase using chitinous scaffolds under hydrothermal conditions. Journal of Materials Chemistry B, 1(38), 5092-5099. doi:10.1039/c3tb20676a.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0015-1E22-1 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0015-1E23-0
Genre: Journal Article

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 Creators:
Ehrlich, H., Author
Simon, P.1, Author              
Motylenko, M., Author
Wysokowski, M., Author
Bazhenov, V. V., Author
Galli, R., Author
Stelling, A. L., Author
Stawski, D., Author
Ilan, M., Author
Stocker, H., Author
Abendroth, B., Author
Born, R., Author
Jesionowski, T., Author
Kurzydlowskii, K. J., Author
Meyer, D. C., Author
Affiliations:
1Paul Simon, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863418              

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 Abstract: Chitinous scaffolds isolated from the skeleton of marine sponge Aplysina cauliformis were used as a template for the in vitro formation of zirconium dioxide nanophase from ammonium zirconium(IV) carbonate (AZC) under extreme conditions (150 degrees C). These novel zirconia-chitin based composites were prepared for the first time using hydrothermal synthesis, and were thoroughly characterized using a plethora of analytical methods. The thermostability of the chitinous 3D matrix makes it ideal for use in the hydrothermal synthesis of monoclinic nanostructured zirconium dioxide from precursors like AZC. These zirconium-chitin composites have a high potential for use in a broad range of applications ranging from synthetic catalysis to biocompatible materials for bone and dental repair. The synthetic methods presented in this work show an attractive route for producing monoclinic zirconium dioxide on a 3D biocompatible scaffold with ease.

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Language(s): eng - English
 Dates: 2013-11-08
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: eDoc: 670758
ISI: 000324425600023
DOI: 10.1039/c3tb20676a
 Degree: -

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Title: Journal of Materials Chemistry B
Source Genre: Journal
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Publ. Info: -
Pages: - Volume / Issue: 1 (38) Sequence Number: - Start / End Page: 5092 - 5099 Identifier: ISSN: 2050-750X