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  Synthesis, characterization, and thermal behavior of Cu(II) and Zn(II) complexes with (E)-2-[N'-(1-pyridin-2-yl-ethylidene)hydrazino]acetic acid (aphaOH). Crystal structure of [Zn2(aphaO)2Cl2]

Filipovic, N., Borna, M., Klisuric, O., Pregelj, M., Jagodic, M., Andelkovic, K., et al. (2013). Synthesis, characterization, and thermal behavior of Cu(II) and Zn(II) complexes with (E)-2-[N'-(1-pyridin-2-yl-ethylidene)hydrazino]acetic acid (aphaOH). Crystal structure of [Zn2(aphaO)2Cl2]. Journal of Coordination Chemistry, 66(9), 1549-1560. doi:10.1080/00958972.2013.786052.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0015-1FB2-8 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0015-1FB3-6
Genre: Journal Article

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 Creators:
Filipovic, N., Author
Borna, M.1, Author              
Klisuric, O., Author
Pregelj, M., Author
Jagodic, M., Author
Andelkovic, K., Author
Todorovic, T., Author
Affiliations:
1Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863404              

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 Abstract: Copper(II) and zinc(II) complexes with the condensation derivative of 2-acetylpyridine and hydrolyzed ethyl hydrazinoacetate were synthesized in a one pot reaction. Crystal structure of the zinc(II) complex was determined by single-crystal X-ray diffraction. In this binuclear complex, the ligand is coordinated via pyridine and imine nitrogen, while carboxylate oxygen is a bridge between metal centers. The fifth coordination site is occupied by a chloride, giving a distorted square pyramidal geometry around each zinc(II). The molecular structure of the copper(II) complex was determined from elemental analysis, infrared and electron paramagnetic resonance spectroscopy, molar conductivity, mass spectrometry, and measurements of the magnetic moment. Thermal behavior of both complexes was studied by thermogravimetric analysis coupled with mass spectrometer.

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Language(s): eng - English
 Dates: 2013-01-10
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: eDoc: 667526
ISI: 000318280000008
DOI: 10.1080/00958972.2013.786052
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Title: Journal of Coordination Chemistry
Source Genre: Journal
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Affiliations:
Publ. Info: -
Pages: - Volume / Issue: 66 (9) Sequence Number: - Start / End Page: 1549 - 1560 Identifier: ISSN: 0095-8972