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  Eu valence changes by the interplay of chemical potential, disorder and pressure: a joint theoretical and experimental study of EuPd3Bx and Eu1-xLaxPd3

Schmitt, M., Gumeniuk, R., Leithe-Jasper, A., Schwarz, U., Rosner, H., & Trapananti, A. (2011). Eu valence changes by the interplay of chemical potential, disorder and pressure: a joint theoretical and experimental study of EuPd3Bx and Eu1-xLaxPd3. Diffusion and Defect Data Part B (Solid State Phenomena), 170: S-03-P-75, pp. 465-465.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0015-224B-8 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0015-224D-4
Genre: Journal Article

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 Creators:
Schmitt, M.1, Author              
Gumeniuk, R.2, Author              
Leithe-Jasper, A.3, Author              
Schwarz, U.4, Author              
Rosner, H.5, Author              
Trapananti, A., Author
Affiliations:
1Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863404              
2Roman Gumeniuk, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863421              
3Andreas Leithe-Jasper, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863406              
4Ulrich Schwarz, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863423              
5Helge Rosner, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863450              

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 Abstract: Ab-initio band structure calculations for EuPd 3B x combined with XRD and XAS measurements for different B contents as well as under high pressure were conducted. The results obtained a subtle interplay between doping and volume effects on the valence instability, whereas the disorder is less relevant. With this calculational approach, a stable Eu 2+ valence in Eu 0.4La 0.6Pd 3 due to the La insertion was observed.

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 Dates: 2011-06-30
 Publication Status: Published in print
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 Table of Contents: -
 Rev. Method: -
 Identifiers: eDoc: 609662
ISI: 12563583
 Degree: -

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Title: Diffusion and Defect Data Part B (Solid State Phenomena)
  Alternative Title : Diffus. Defect Data B, Solid State Phenom. (Switzerland)
Source Genre: Journal
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Pages: - Volume / Issue: 170 Sequence Number: S-03-P-75 Start / End Page: 465 - 465 Identifier: ISSN: 1012-0394