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  Synthesis and Crystal Structure of KSc(HPO4)2

Menezes, P. W., Hoffmann, S., Prots, Y., & Kniep, R. (2009). Synthesis and Crystal Structure of KSc(HPO4)2. Zeitschrift für Anorganische und Allgemeine Chemie, 635, 33-35. doi:10.1002/zaac.200800395.

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 Creators:
Menezes, P. W.1, Author           
Hoffmann, S.1, Author           
Prots, Y.2, Author           
Kniep, R.3, Author           
Affiliations:
1Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863404              
2Yuri Prots, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863424              
3Rüdiger Kniep, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863437              

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Free keywords: Scandium; Potassium; Phosphate; Channels
 Abstract: KSc(HPO4)(2) was obtained by hydrothermal synthesis. The crystal structure was determined from single-crystal X-ray data: orthorhombic. space group Pnma (No. 62), a = 14.5095(10). b = 5.4260(4). c = 8.4882(5) angstrom, V = 668.26(8) angstrom(3) and Z = 4. The crystal structure of KSc(HPO4)(2) represents a new structure type containing twelve- and four-membered rings forming channels along [010] built of alternating ScO6 octahedra and HPO42- groups. Potassium ions reside within the twelve membered ring channels.

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Language(s): eng - English
 Dates: 2009
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: eDoc: 404371
ISI: 000262738500003
DOI: 10.1002/zaac.200800395
 Degree: -

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Title: Zeitschrift für Anorganische und Allgemeine Chemie
Source Genre: Journal
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Pages: - Volume / Issue: 635 Sequence Number: - Start / End Page: 33 - 35 Identifier: ISSN: 0044-2313