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  (Sr2N)H: Untersuchungen zur Redox-Intercalation von Wasserstoff in Sr2N

Chemnitzer, R., Auffermann, G., Többens, D. M., & Kniep, R. (2005). (Sr2N)H: Untersuchungen zur Redox-Intercalation von Wasserstoff in Sr2N. Zeitschrift für anorganische und allgemeine Chemie, 631(10), 1813-1817. doi:10.1002/zaac.200500105.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0015-2C87-1 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0019-EAB0-8
Genre: Journal Article

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 Creators:
Chemnitzer, R.1, Author              
Auffermann, G.2, Author              
Többens, D. M., Author
Kniep, R.3, Author              
Affiliations:
1Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863404              
2Gudrun Auffermann, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863432              
3Rüdiger Kniep, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863437              

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 Abstract: Strontium-nitride-hydride is obtained as brown-yellow single phase powder by reaction of strontium-subnitride (Sr2N) with hydrogen (200 bar, 620 K) and subsequent treatment under vacuum (10−6 bar, 870 K). The structure determination was carried out by a combination of X-ray and neutron diffraction experiments on a deuterated sample. The elemental composition of the ternary compound was confirmed by means of chemical analyses. (Sr2N)D crystallizes in the space group equation image with a = 381.91(2) pm and c = 1887.61(2) pm. Strontium (Sr2+) in the crystal structure of (Sr2N)D is arranged with an only slightly distorted ccp-motif. Nitrogen (N3−) and deuterium (D−) occupy the octahedral voids of the Sr2+-matrix in an ordered manner resulting in an alternating sequence of layers (anti-α-NaFeO2-type structure).

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Language(s): deu - German
 Dates: 2005-08-01
 Publication Status: Published in print
 Pages: -
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 Table of Contents: -
 Rev. Method: -
 Identifiers: eDoc: 237914
DOI: 10.1002/zaac.200500105
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Title: Zeitschrift für anorganische und allgemeine Chemie
  Other : Zeitschrift fuer Anorganische und Allgemeine Chemie
  Other : Journal of Inorganic and General Chemistry
  Other : J. Inorg. Gen Chem.
  Abbreviation : Z. Anorg. Allg. Chem.
Source Genre: Journal
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Publ. Info: Weinheim : WILEY-VCH Verlag GmbH & Co. KGaA
Pages: - Volume / Issue: 631 (10) Sequence Number: - Start / End Page: 1813 - 1817 Identifier: ISSN: 0044-2313
CoNE: /journals/resource/954925453895