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  Phosphorus-31 MAS NMR investigations of pyridine stabilized dithiomonometaphosphoryl halides

Rabis, A., Grimmer, A.-R., Thomas, B., Brendler, E., Beck, S., & Meisel, M. (2005). Phosphorus-31 MAS NMR investigations of pyridine stabilized dithiomonometaphosphoryl halides. Solid State Nuclear Magnetic Resonance, 28(1), 57-63. doi:10.1016/j.ssnmr.2005.06.001.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0015-2C8D-6 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0019-EAB6-B
Genre: Journal Article

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 Creators:
Rabis, A.1, Author              
Grimmer, A.-R., Author
Thomas, B., Author
Brendler, E., Author
Beck, S., Author
Meisel, M., Author
Affiliations:
1Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863404              

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 Abstract: Phosphorus-31 magic-angle spinning NMR spectroscopy was chosen in order to study a series of N-donor stabilized dithiomonometaphosphoryl halides (F, Cl, and Br) and to extract structural and bonding information from their spectra. Additionally, an unusual line splitting was observed in the 31P MAS NMR spectra of pyridine dithiomonometaphosphoryl chloride (Py→PS2Cl) and the analogous bromide (Py→PS2Br). It is shown that this effect is due to a residual dipolar coupling between phosphorus and chlorine or bromine, respectively. This work is to our knowledge the first observation of this effect between P and Br in 31P MAS NMR spectra.

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Language(s): eng - English
 Dates: 2005-07-01
 Publication Status: Published in print
 Pages: -
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 Table of Contents: -
 Rev. Method: -
 Identifiers: eDoc: 239908
DOI: 10.1016/j.ssnmr.2005.06.001
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Title: Solid State Nuclear Magnetic Resonance
Source Genre: Journal
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Publ. Info: San Diego, CA : Academic Press
Pages: - Volume / Issue: 28 (1) Sequence Number: - Start / End Page: 57 - 63 Identifier: ISSN: 0926-2040
CoNE: /journals/resource/954925567752