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  New lead vanadium phosphate with langbeinite-type structure: Pb1.5V2(PO4)3

Shpanchenko, R. V., Lapshina, O. A., Antipov, E. V., Hadermann, J., Kaul, E. E., & Geibel, C. (2005). New lead vanadium phosphate with langbeinite-type structure: Pb1.5V2(PO4)3. Materials Research Bulletin, 40(9), 1569-1576. doi:10.1016/j.materresbull.2005.04.037.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0015-2CA9-6 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0019-EAEE-D
Genre: Journal Article

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 Creators:
Shpanchenko, R. V., Author
Lapshina, O. A., Author
Antipov, E. V., Author
Hadermann, J.1, Author              
Kaul, E. E.1, Author              
Geibel, C.2, Author              
Affiliations:
1Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863404              
2Christoph Geibel, Physics of Quantum Materials, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863465              

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 Abstract: The new lead vanadium phosphate Pb1.5V2(PO4)3 was synthesized by solid state reaction and characterized by X-ray powder diffraction, electron microscopy, and magnetic susceptibility measurements. The crystal structure of Pb1.5V2(PO4)3 (a = 9.78182(8) Å, S.G. P213, Z = 4) was determined from X-ray powder diffraction data and belongs to the langbeinite-type structures. It is formed by corner-linked V3+O6 octahedra and tetrahedral phosphate groups resulting in a three-dimensional framework. The lead atoms are situated in the structure interstices and only partially occupy their positions. An electron microscopy study confirmed the structure solution. Magnetic susceptibility measurements revealed Curie–Weiss (CW) behavior for Pb1.5V2(PO4)3 at high temperature whereas at around 14 K an abrupt increase on the susceptibility was observed.

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Language(s): eng - English
 Dates: 2005
 Publication Status: Published in print
 Pages: -
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 Table of Contents: -
 Rev. Method: -
 Identifiers: eDoc: 241716
DOI: 10.1016/j.materresbull.2005.04.037
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Title: Materials Research Bulletin
Source Genre: Journal
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Publ. Info: Oxford : Pergamon
Pages: - Volume / Issue: 40 (9) Sequence Number: - Start / End Page: 1569 - 1576 Identifier: ISSN: 0025-5408
CoNE: /journals/resource/954926251623