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  Crystal Structure, Chemical Bonding, and Phase Relations of the Novel Compound Co4Al7+xSi2-x(0.27 ≤ x ≤ 1.05)

Richter, K. W., Prots, Y., & Grin, Y. (2005). Crystal Structure, Chemical Bonding, and Phase Relations of the Novel Compound Co4Al7+xSi2-x(0.27 ≤ x ≤ 1.05). Inorganic Chemistry, 44(13), 4576-4585. doi:10.1021/ic0401243.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0015-2CB5-A Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0019-EB08-9
Genre: Journal Article

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 Creators:
Richter, K. W., Author
Prots, Y.1, Author           
Grin, Y.2, Author           
Affiliations:
1Yuri Prots, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863424              
2Juri Grin, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863413              

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 Abstract: The title compound represents a new type of structure for intermetallic compounds (Pearson symbol mC26, space group C2/m). Partial disorder caused by the Al/Si substitution in one of the five main group element positions may be described by several ordering models yielding different Al/Si occupation motifs and different distributions of interatomic distances. Chemical bonding analysis with the electron localization function (ELF) reveals a covalently bonded Al/Si network and rather ionic interactions between Co and the network.

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Language(s): eng - English
 Dates: 2005-05-01
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: eDoc: 241724
DOI: 10.1021/ic0401243
 Degree: -

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Title: Inorganic Chemistry
  Abbreviation : Inorg. Chem.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 44 (13) Sequence Number: - Start / End Page: 4576 - 4585 Identifier: ISSN: 0020-1669
CoNE: https://pure.mpg.de/cone/journals/resource/0020-1669