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  Cs2[PdCl4] - neue Ergebnisse zu einer "altbekannten" Verbindung

Schüpp, B., Schröder, L., Schulte, H., Bähtz, C., Mattern, N., & Keller, H. L. (2002). Cs2[PdCl4] - neue Ergebnisse zu einer "altbekannten" Verbindung. Zeitschrift für anorganische und allgemeine Chemie, 628(7), 1708-1714. doi:10.1002/1521-3749(200207)628:7<1708:AID-ZAAC1708>3.0.CO;2-A.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0015-313F-B Version Permalink: http://hdl.handle.net/11858/00-001M-0000-002D-4F8A-C
Genre: Journal Article
Alternative Title : Cs2[PdCl4] - New results on a "wellkown" compound

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 Creators:
Schüpp, B., Author
Schröder, L.1, Author              
Schulte, H., Author
Bähtz, C., Author
Mattern, N., Author
Keller, H. L., Author
Affiliations:
1Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863425              

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Free keywords: cesium; palladium; dicesiumtetrachloropalladate(II)
 Abstract: Two modifications of Cs-2[PdCl4] have been characterized by X- ray powder and single crystal diffraction, respectively. The crystal structures are described and the group-subgroup- relations between these structures are discussed. In addition to the tetragonal (P4/mmm (No. 123), a 7.4158(8) Angstrom, c = 4.6792(6) Angstrom) and the orthorhombic (Cmcm (No. 63), a = 10.529(1) Angstrom, b = 10.310(1) Angstrom, c = 9.460(1) Angstrom) modification DSC investigations and high-temperature X-ray diffraction experiments with synchrotron radiation show the existence of another modification or of yet unknown decomposition products. The phase transformation from the orthorhombic to the tetragonal polymorph is completely finished at 100degreesC. The second effect is detected at 319degreesC.

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Language(s): deu - German
 Dates: 2002-07
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Degree: -

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Title: Zeitschrift für anorganische und allgemeine Chemie
  Other : Journal of Inorganic and General Chemistry
  Other : J. Inorg. Gen Chem.
  Abbreviation : Z. Anorg. Allg. Chem.
Source Genre: Journal
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Publ. Info: Leipzig, Weinheim : Verlag Johann Ambrosius Barth / Wiley-VCH
Pages: - Volume / Issue: 628 (7) Sequence Number: - Start / End Page: 1708 - 1714 Identifier: Other: 1521-3749
ISSN: 0044-2313
CoNE: https://pure.mpg.de/cone/journals/resource/954925453895