English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Large Orbital Moments and Internal Magnetic Fields in Lithium Nitridoferrate(I)

Klatyk, J., Schnelle, W., Wagner, F. R., Niewa, R., Novak, P., Kniep, R., et al. (2002). Large Orbital Moments and Internal Magnetic Fields in Lithium Nitridoferrate(I). Physical Review Letters, 88(20): 207202, pp. 207202-207202. doi:10.1103/PhysRevLett.88.207202.

Item is

Basic

show hide
Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0015-314F-7 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0017-FF89-A
Genre: Journal Article

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Klatyk, J.1, Author              
Schnelle, W.2, Author              
Wagner, F. R.3, Author              
Niewa, R.1, Author              
Novak, P., Author
Kniep, R.4, Author              
Waldeck, M., Author
Ksenofontov, V., Author
Gütlich, P., Author
Affiliations:
1Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863404              
2Walter Schnelle, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863441              
3Frank Wagner, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863409              
4Rüdiger Kniep, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863437              

Content

show
hide
Free keywords: -
 Abstract: The iron nitridometalates Li-2[ (Li1-x Fe (I)(x))N] display ferromagnetic ordering and spin freezing. Large magnetic moments up to 5.0mu(B)/Fe are found in the magnetization. In Mossbauer effect studies huge hyperfine magnetic fields up to 696 kOe are observed at specific Fe sites. These extraordinary fields and moments originate in an unusual ligand field splitting for those Fe species leading [within local spin density approximation (LSDA)] to a localized orbitally degenerate doublet. Including spin-orbit interaction and strong intra-atomic electron correlation (LDA+SO+U) gives rise to a large orbital momentum.

Details

show
hide
Language(s): eng - English
 Dates: 2002-05-20
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: Peer
 Identifiers: eDoc: 17702
ISI: 000175466200043
DOI: 10.1103/PhysRevLett.88.207202
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Physical Review Letters
  Alternative Title : Phys. Rev. Lett.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: -
Pages: - Volume / Issue: 88 (20) Sequence Number: 207202 Start / End Page: 207202 - 207202 Identifier: ISSN: 0031-9007