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  Hidden flexibility of strychnine.

Schmidt, M., Reinscheid, F., Sun, H., Abromeit, H., Scriba, G. K. E., Soennichsen, F. D., et al. (2014). Hidden flexibility of strychnine. European Journal of Organic Chemistry, 2014(6), 1147-1150. doi:10.1002/ejoc.201301760.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0017-BF53-8 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0027-CBDF-D
Genre: Journal Article

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1949845.pdf (Publisher version), 319KB
 
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 Creators:
Schmidt, M.1, Author              
Reinscheid, F.1, Author              
Sun, H.1, Author              
Abromeit, H., Author
Scriba, G. K. E., Author
Soennichsen, F. D., Author
John, M., Author
Reinscheid, U. M.1, Author              
Affiliations:
1Department of NMR Based Structural Biology, MPI for Biophysical Chemistry, Max Planck Society, ou_578567              

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Free keywords: Conformation analysis; NMR spectroscopy; Density functional calculations; Dynamic stereochemistry; Natural products
 Abstract: The prototypic molecule for conformational rigidity, that is, strychnine, exhibits fast conformational exchange on the NMR timescale at room temperature. A comprehensive description of this up-to-now-hidden stereodynamic behavior is presented, which combines experimental and computational data.

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Language(s): eng - English
 Dates: 2014-01-152014-02
 Publication Status: Published in print
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 Rev. Method: Peer
 Identifiers: DOI: 10.1002/ejoc.201301760
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Title: European Journal of Organic Chemistry
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Source Genre: Journal
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Pages: - Volume / Issue: 2014 (6) Sequence Number: - Start / End Page: 1147 - 1150 Identifier: -