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  Ternary Rare-Earth Transition-Metal Polyhydride Cluster Compounds

Bauer, T., Wagner, F. R., & Kempe, R. (2013). Ternary Rare-Earth Transition-Metal Polyhydride Cluster Compounds. Chemistry - A European Journal, 19(27), 8732-8735. doi:10.1002/chem.201301290.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0018-09A0-3 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0018-09A2-0
Genre: Journal Article

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 Creators:
Bauer, Tobias1, Author
Wagner, Frank R.2, Author              
Kempe, Rhett1, Author
Affiliations:
1external, ou_persistent22              
2Frank Wagner, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863409              

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 Abstract: Combining three: The first examples of ternary rare-earth transition-metal polyhydride clusters (see figure) are reported. Cluster formation proceeds through C[BOND]H bond activation of the Cp ligands that stabilize the transition-metal-containing starting material. Analysis of the electronic structure of the polyhydride cluster compounds revealed covalent Re[BOND]Lu bonding and ionic transition metal hydride–Lu interactions.

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 Dates: 2013-06-11
 Publication Status: Published in print
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 Table of Contents: -
 Rev. Method: -
 Identifiers: ISI: 000320782400003
DOI: 10.1002/chem.201301290
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Title: Chemistry - A European Journal
  Other : Chem. Eur. J.
Source Genre: Journal
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Publ. Info: Weinheim, Germany : VCH Verlagsgesellschaft
Pages: - Volume / Issue: 19 (27) Sequence Number: - Start / End Page: 8732 - 8735 Identifier: ISSN: 0947-6539
CoNE: /journals/resource/954926979058