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  Kinetics of the Chiral Disulfonimide-Catalyzed Mukaiyama Aldol Reaction

Zhang, Z., & List, B. (2013). Kinetics of the Chiral Disulfonimide-Catalyzed Mukaiyama Aldol Reaction. Asian Journal of Organic Chemistry, 2(11), 957-960. doi:10.1002/ajoc.201300182.

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 Creators:
Zhang, Zhipeng1, Author              
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

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Free keywords: disulfonimides; kinetics; Mukaiyama aldol reaction; organocatalysis; reaction progress kinetic analysis
 Abstract: Making progress: The kinetics of the disulfonimide-catalyzed Mukaiyama aldol reaction have been established by using the reaction progress kinetic analysis (RPKA) method. The reaction is first order with respect to catalyst and silyl ketene acetal, and has an order of 0.55 with respect to the aldehyde, which suggests the reversibility of the binding between the aldehyde and the actual catalyst.

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Language(s): eng - English
 Dates: 2013-09-132013-11-01
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/ajoc.201300182
 Degree: -

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Title: Asian Journal of Organic Chemistry
  Abbreviation : Asian J. Org. Chem.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 2 (11) Sequence Number: - Start / End Page: 957 - 960 Identifier: ISSN: 2193-5815
CoNE: https://pure.mpg.de/cone/journals/resource/2193-5815