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  Electronic properties of the triplet state of fluorene, carbazole, dibenzofuran and dibenzothiophene(X-traps)

Goldacker, W., Schweitzer, D., & Zimmermann, H. (1979). Electronic properties of the triplet state of fluorene, carbazole, dibenzofuran and dibenzothiophene(X-traps). Chemical Physics, 36(1), 15-26. doi:10.1016/0301-0104(79)85100-9.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0019-B0A9-9 Version Permalink: https://hdl.handle.net/21.11116/0000-0001-22AD-6
Genre: Journal Article

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ChemPhys_36_1979_15.pdf (Any fulltext), 2MB
 
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 Creators:
Goldacker, W.1, Author           
Schweitzer, Dieter1, Author           
Zimmermann, Herbert1, 2, 3, 4, Author           
Affiliations:
1Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society, ou_1497705              
2Department of Biomolecular Mechanisms, Max Planck Institute for Medical Research, Max Planck Society, ou_1497700              
3Zimmermann Group, Max Planck Institute for Medical Research, Max Planck Society, ou_1497749              
4Emeritus Group Biophysics, Max Planck Institute for Medical Research, Max Planck Society, ou_1497712              

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 Abstract: The triplet state of X-traps in neat single crystals of fluorene, carbazole, dibenzofuran and dibenzothiophene was investigated bv the method of ODMR in zero field at 1.3 K. In addition to the intersystem crossing rates, steady state populations, decay rate constants and relative radiative rate constants of the sublevels, the spin-lattice relaxation (SLR)-rates were measured. which could not be neglected even at this low temperature. In the case of dibenzothiophene a strong intramolecular heavy-atom effect due to the sulphur atom was observed which allowed direct So → T1 excitation.

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Language(s): eng - English
 Dates: 1978-08-112001-11-121979-01-01
 Publication Status: Issued
 Pages: 12
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/0301-0104(79)85100-9
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Title: Chemical Physics
  Other : Chem. Phys.
Source Genre: Journal
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Publ. Info: Amsterdam : Elsevier B.V.
Pages: - Volume / Issue: 36 (1) Sequence Number: - Start / End Page: 15 - 26 Identifier: ISSN: 0301-0104
CoNE: https://pure.mpg.de/cone/journals/resource/954925509371