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  13C Anisotropic chemical shift in a single crystal of benzophenone

Kempf, J., Spiess, H. W., Haeberlen, U., & Zimmermann, H. (1972). 13C Anisotropic chemical shift in a single crystal of benzophenone. Chemical Physics Letters, 17(1), 39-42. doi:10.1016/0009-2614(72)80318-X.

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Genre: Journal Article
Alternative Title : 13C Anisotropic chemical shift in a single crystal of benzophenone

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ChemPhysLett_17_1972_39.pdf (Any fulltext), 342KB
 
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Kempf, J.1, Author              
Spiess, Hans W.1, Author              
Haeberlen, Ulrich2, Author              
Zimmermann, Herbert1, 3, 4, 5, Author              
Affiliations:
1Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society, ou_1497705              
2Research Group Prof. Dr. Haeberlen, Max Planck Institute for Medical Research, Max Planck Society, ou_1497739              
3Department of Biomolecular Mechanisms, Max Planck Institute for Medical Research, Max Planck Society, ou_1497700              
4Zimmermann Group, Max Planck Institute for Medical Research, Max Planck Society, ou_1497749              
5Emeritus Group Biophysics, Max Planck Institute for Medical Research, Max Planck Society, ou_1497712              

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 Abstract: The 13C resonance of the carbonyl carbon in a single crystal of benzophenone was studied by Fourier transform NMR at room temperature. Rotation patterns about the three cyrstallographic axes yielded the orientations of the major axis systems of the chemical shift tensor σ relative to the crystallographic axes for the four molecules in the unit cell. The principal elements of σ were found to be: σxx = −79 ± 4, σyy = −36 ± 4, and σzz = +94 ± 4 ppm , relative to CS2. The Z axis of the nearly axially symmetric σ tensor was found to be perpendicular to the plane spanned by the carbonyl carbon and the carbon and oxygen atoms directly bound to it.

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Language(s): eng - English
 Dates: 1972-07-312001-12-211972-11-01
 Publication Status: Published in print
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 Rev. Type: Peer
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Title: Chemical Physics Letters
  Alternative Title : Chem. Phys. Lett.
Source Genre: Journal
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Pages: - Volume / Issue: 17 (1) Sequence Number: - Start / End Page: 39 - 42 Identifier: -