hide
Free keywords:
-
Abstract:
The combination of the [Co-III(Cl-2-bpy)(3)](3+) complex with the [Ni(dmit)(2)](-) anion is a one-step reaction, which results in the partially oxidised Ni(dmit)(2)-based material [Co-II(C;(2)-bpy)(3)][Ni(dmit)(2)](5) with a paramagnetic Con cation, as proven by Raman, EPR and XAS, exemplifying a, for M(dithiolene)(2) compounds new, synthetic strategy that may give access to a large variety of new [Co-II(N,N-imine)(3)][M(dithiolene)(2)] (n > 2, M = Ni, Pd) type magnetic conductors.
