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  Enhanced sensitivity of electron-nuclear double resonance (ENDOR) by cross polarisation and relaxation.

Rizzato, R., & Bennati, M. (2014). Enhanced sensitivity of electron-nuclear double resonance (ENDOR) by cross polarisation and relaxation. Physical Chemistry Chemical Physics, 16(17), 7681-7685. doi:10.1039/C3CP55395G.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0019-1A32-1 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0027-CCC6-C
Genre: Journal Article

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 Creators:
Rizzato, R.1, Author              
Bennati, M.1, Author              
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1Research Group of Electron Paramagnetic Resonance, MPI for Biophysical Chemistry, Max Planck Society, ou_578606              

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 Abstract: Electron-nuclear double resonance (ENDOR) is a method of choice to detect magnetic nuclei in the coordination sphere of paramagnetic molecules, but its sensitivity substantially suffers from saturation effects. Recently we introduced a new pulsed ENDOR experiment based on electron-nuclear cross polarisation (CP) transfer. Here we analyse the time evolution of the spin polarization in CP-ENDOR and show that CP combined with inherent fast relaxation leads to enhanced sensitivity as compared to Davies ENDOR.

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Language(s): eng - English
 Dates: 2014-03-032014-05-07
 Publication Status: Published in print
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 Rev. Method: Peer
 Identifiers: DOI: 10.1039/C3CP55395G
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Title: Physical Chemistry Chemical Physics
Source Genre: Journal
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Pages: - Volume / Issue: 16 (17) Sequence Number: - Start / End Page: 7681 - 7685 Identifier: -