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  Complex Ternary Transition-Metal Hydrides and Hydridometalates

Auffermann, G., & Bronger, W. (2013). Complex Ternary Transition-Metal Hydrides and Hydridometalates. In J. Reedijk, & K. Poeppelmeier (Eds.), Comprehensive Inorganic Chemistry II (Second Edition) (pp. 583-599). Amsterdam: Elsevier. doi:10.1016/j.bbr.2011.03.031.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0019-1AE4-4 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0019-1B02-9
Genre: Book Chapter

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 Creators:
Auffermann, G.1, Author              
Bronger, W.2, Author              
Affiliations:
1Gudrun Auffermann, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863432              
2Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863404              

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Free keywords: Alkali metal, Alkaline-earth metal, Coordination geometry, Crystal structure, Hydride, Hydridometalate, Neutron diffraction, Order–disorder transition, Rare-earth metal, Reaction pressure
 Abstract: Various preparation routes led to a large number of complex ternary transition-metal hydrides and hydridometalates containing d- and f-elements, together with alkali, alkaline-earth, and rare-earth metals. Here, the parameter pressure is a crucial tool for the selective synthesis: increasing the reaction pressure leads to higher oxidation states of the transition element. The crystal structures of hydridometalates show a broad variety of different complex formations, whereby higher valence states of transition metals are favored, with alkali metal as the counterion. Moreover, the mobility of hydrogen atoms causes numerous order–disorder transitions.

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Language(s): eng - English
 Dates: 20132013
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Degree: -

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Title: Comprehensive Inorganic Chemistry II (Second Edition)
Source Genre: Multi-Volume
 Creator(s):
Reedijk, Jan, Editor
Poeppelmeier , Kenneth, Editor
Affiliations:
-
Publ. Info: Amsterdam : Elsevier
Pages: - Volume / Issue: Volume 2: Transition Elements, Lanthanides and Actinides Sequence Number: - Start / End Page: 583 - 599 Identifier: -