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  Low-Valency Nitridometalates

Kniep, R., & Höhn, P. (2013). Low-Valency Nitridometalates. In J. Reedijk, & K. Poeppelmeier (Eds.), Comprehensive Inorganic Chemistry II (Second Edition) (pp. 137-160). Amsterdam: Elsevier. doi:10.1016/B978-0-08-097774-4.00206-0.

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 Creators:
Kniep, R.1, Author           
Höhn, P.2, Author           
Affiliations:
1Rüdiger Kniep, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863437              
2Peter Höhn, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863419              

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Free keywords: Alkali metals, Alkaline earth metals, Chemical bonding, Complex anions, Crystal structure, Low valency, Nitridometalates, Physical properties, Preparation, Structure–property relations, Substitution
 Abstract: The tendency to stabilize low oxidation states of transition metals in compounds containing complex anions and monoatomic nonmetal ligands increases with the ligand sequence F− → O2 − → N3 − → C4 −. In the case of nitridometalates, the oxidation states of the transition metals reach the low level of + 1 (in some cases, even <+ 1), characterized by the formation of complex anions in the form of dumbbells, infinite chains (various conformations), and layers. Preparative aspects are discussed in detail, together with substitution szenarios, crystal structures, chemical bonding, and physical properties. Future trends include the role of carbon during nitridometalate synthesis.

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Language(s): eng - English
 Dates: 20132013
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Degree: -

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Title: Comprehensive Inorganic Chemistry II (Second Edition)
Source Genre: Multi-Volume
 Creator(s):
Reedijk, Jan, Editor
Poeppelmeier, Kenneth, Editor
Affiliations:
-
Publ. Info: Amsterdam : Elsevier
Pages: - Volume / Issue: Volume 2: Transition Elements, Lanthanides and Actinides Sequence Number: - Start / End Page: 137 - 160 Identifier: -