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  New scandium rhodium boride Sc4Rh17B12 with a framework structure: synthesis, crystal structure, and properties

Alekseeva, A. M., Leithe-Jasper, A., Prots, Y., Schnelle, W., Grin, Y., & Antipov, E. V. (2008). New scandium rhodium boride Sc4Rh17B12 with a framework structure: synthesis, crystal structure, and properties. Russian Chemical Bulletin, 57(3), 532-540. doi:10.1007/s11172-008-0082-z.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0019-80AB-1 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0019-80AD-E
Genre: Journal Article

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 Creators:
Alekseeva, A. M.1, Author              
Leithe-Jasper, A.2, Author              
Prots, Yu.3, Author              
Schnelle, W.4, Author              
Grin, Yu.5, Author              
Antipov, E. V.6, Author
Affiliations:
1Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863404              
2Andreas Leithe-Jasper, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863406              
3Yuri Prots, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863424              
4Walter Schnelle, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863441              
5Juri Grin, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863413              
6external, ou_persistent22              

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 Abstract: The new scandium rhodium boride Sc4Rh17B12 was synthesized by arc-melting of the elements followed by annealing in inert atmosphere. The crystal structure of Sc4Rh17B12 was solved using single crystal X-ray diffraction data. The structure can be described as a three-dimensional framework formed by trigonal prisms [BRh6] and [BRh5Sc] with isolated boron atoms inside the prisms and trigonal prisms [BRh5B] representing the coordination polyhedra of paired boron atoms. The temperature dependences of the magnetic Susceptibility and specific resistance of Sc4Rh17B12 revealed that the compound is a Pauli paramagnet and shows metal-like specific resistance.

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 Dates: 2008-03-03
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: ISI: 000263566900012
DOI: 10.1007/s11172-008-0082-z
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Title: Russian Chemical Bulletin
  Other : Russ. Chem. Bull.
Source Genre: Journal
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Publ. Info: New York : Consultants Bureau
Pages: - Volume / Issue: 57 (3) Sequence Number: - Start / End Page: 532 - 540 Identifier: ISSN: 1066-5285
CoNE: /journals/resource/954925601692