English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Infrared Photodissociation Spectroscopy of C2n+1N- Anions with n = 1 – 5

Stanca-Kaposta, E., Schwaneberg, F., Fagiani, M. R., Wende, T., Hagemann, F., Wünschmann, A., et al. (2014). Infrared Photodissociation Spectroscopy of C2n+1N- Anions with n = 1 – 5. Zeitschrift für physikalische Chemie, 228(4-5), 351-368. doi:10.1515/zpch-2014-0507.

Item is

Files

show Files
hide Files
:
Revised_Manuscript2.pdf (Any fulltext), 432KB
 
File Permalink:
-
Name:
Revised_Manuscript2.pdf
Description:
-
Visibility:
Private (embargoed till 2015-05)
MIME-Type / Checksum:
application/pdf
Technical Metadata:
Copyright Date:
2014
Copyright Info:
De Gruyter
License:
-
:
zpch-2014-0507.pdf (Publisher version), 721KB
Name:
zpch-2014-0507.pdf
Description:
-
Visibility:
Public
MIME-Type / Checksum:
application/pdf / [MD5]
Technical Metadata:
Copyright Date:
2014
Copyright Info:
De Gruyter
License:
MPG green OA
:
2030676.pdf (Copyright transfer agreement), 217KB
 
File Permalink:
-
Name:
2030676.pdf
Description:
-
Visibility:
Private
MIME-Type / Checksum:
application/pdf
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-

Locators

show

Creators

show
hide
 Creators:
Stanca-Kaposta, E. Cristina1, Author
Schwaneberg, Falko1, Author
Fagiani, Matias Ruben2, Author              
Wende, Torsten2, 3, Author              
Hagemann, Franz1, Author
Wünschmann, Annett1, Author
Wöste, Ludger1, Author
Asmis, Knut R.2, 4, Author              
Affiliations:
1Freie Universität Berlin, Institut für Experimentalphysik, Arnimallee 14, 14195 Berlin, Germany, ou_persistent22              
2Molecular Physics, Fritz Haber Institute, Max Planck Society, ou_634545              
3Physical and Theoretical Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford OX1 3QZ, United Kingdom, ou_persistent22              
4Wilhelm-Ostwald-Institut, Universität Leipzig, Linnéstr. 2, D-04103 Leipzig, Germany, ou_persistent22              

Content

show
hide
Free keywords: Infrared Photodissociation; Messenger Technique; Gas Phase; Ab Initio Calculations; Scaling Factor
 Abstract: The gas phase vibrational spectroscopy of cryogenically cooled C2n+1N- anions with n = 1 − 5 is investigated in the spectral range of the C≡C and C≡N stretching modes (1850–2400 cm-1) by way of infrared photodissociation (IRPD) spectroscopy of messenger-tagged C2n+1N-· mD2 complexes. The IRPD spectra are assigned based on a comparison to previously reported anharmonic and harmonic CCSD(T) vibrational frequencies and intensities. Experimentally determined and predicted anharmonic vibrational transition energies lie within ± 21 cm-1. For the harmonic CCSD(T)/vqz+ vibrational frequencies a scaling factor of 0.9808 is determined, resulting in comparable absolute deviations. The influence of the D2-messenger molecules on the structure and the IRPD spectrum is found to be small. Compared to the results of previous IR matrix isolation studies additional, in particular weaker, IR-active transitions are identified.

Details

show
hide
Language(s): eng - English
 Dates: 2014-01-172014-04-082014-05-062014-05
 Publication Status: Published in print
 Pages: 18
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1515/zpch-2014-0507
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Zeitschrift für physikalische Chemie
  Other : International Journal of Research in Physical Chemistry and Chemical Physics
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Berlin : De Gruyter
Pages: - Volume / Issue: 228 (4-5) Sequence Number: - Start / End Page: 351 - 368 Identifier: ISSN: 0942-9352
CoNE: https://pure.mpg.de/cone/journals/resource/954925572905_1