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  Reactions of tin(II) halides with tellurium(IV) halides: a new route to subhalides of tellurium

Kniep, R., & Katryniok, D. (1977). Reactions of tin(II) halides with tellurium(IV) halides: a new route to subhalides of tellurium. Journal of the Chemical Society, Dalton Transactions; Royal Society of Chemistry, (20), 2048-2051. doi:10.1039/DT9770002048.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0019-B304-3 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0019-B305-1
Genre: Journal Article

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Kniep, Rüdiger1, Author              
Katryniok, Detlef2, Author
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1External Organizations, ou_persistent22              
2external, ou_persistent22              

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 Abstract: Reactions of SnX2 with TeX4(X = Cl, Br, or I) have been monitored by differential thermal analysis in closed tubes, and the products identified by their X-ray powder patterns. In the course of the reactions, SnII is always oxidized to SnIV. In the chloride system, TeIV is reduced to elemental Te, whereas in the bromide system the subhalide Te2Br and in the iodide system the subhalide Tel (α and / or β modification) are formed. An excess of SnII causes further reduction of the subhalides to elemental Te.

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 Dates: 1977-05-04
 Publication Status: Published in print
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 Identifiers: DOI: 10.1039/DT9770002048
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Title: Journal of the Chemical Society, Dalton Transactions; Royal Society of Chemistry
Source Genre: Journal
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Pages: - Volume / Issue: (20) Sequence Number: - Start / End Page: 2048 - 2051 Identifier: -