LiSr2 [CoN2]: Ein Nitridocobaltat(I) mit gestreckten Anionen [CoN2]5-

Höhn, P.; Kniep, R.

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LiSr₂ [CoN₂]: Ein Nitridocobaltat(I) mit gestreckten Anionen [CoN₂]^5-

Höhn, P., & Kniep, R. (1992). LiSr₂ [CoN₂]: Ein Nitridocobaltat(I) mit gestreckten Anionen [CoN₂]^5-. Zeitschrift für Naturforschung Section B-A Journal of Chemical Sciences, 47(3), 434-436.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0019-B843-F Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0019-B844-D

Genre: Journal Article

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Höhn, P.¹, Author
Kniep, R.², Author

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2External Organizations, ou_persistent22

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Abstract: LiSr2[CoN2] (tetrag., P4(2)/mnm (Nr. 136); a = 524.4(1) pm, c = 730.7(2) pm; Z = 2) was prepared by reaction of mixtures of Li, Sr2N and Co (molar ratio 6:3:1) in tantalum crucibles under nitrogen (1 atm) at 850-degrees-C. The crystal structure (alpha-Li3[BN2]-type) contains linear anions [CoIN2]5- (Co-N: 181.0(5) pm) which are isostructural to [FeIIN2]4- (Li4[FeN2]) as well as to the maingroup species CO2 and [BN2]3-.

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Dates: Date issued: 1992-10-20

Publication Status: Issued

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Identifiers: ISI: A1992HK23600022

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Title: Zeitschrift für Naturforschung Section B-A Journal of Chemical Sciences

Other : Z.Naturforsch.(B)

Source Genre: Journal

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Publ. Info: Tübingen : Verlag der Zeitschrift für Naturforschung

Pages: - Volume / Issue: 47 (3) Sequence Number: - Start / End Page: 434 - 436 Identifier: ISSN: 0932-0776
CoNE: https://pure.mpg.de/cone/journals/resource/954925569815