ausblenden:
Schlagwörter:
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Zusammenfassung:
Using the possibility to produce Co-61 sources at the MAinz MIcrotron,
Ni-61 Mossbauer spectroscopy was applied to different kinds of chemical
problems. Measurements of isomer shifts and V-zz values in some common
compounds and compounds with unusual chemical bonding for comparison
with band structure calculations, measurement of Ni-61 Mossbauer
parameters in model compounds for hydrogenase and dehydrogenase with an
active [NiS4] centre, and study of novel binary NiF3 compounds at helium
temperature are presented.