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  (Sr6N)[Ga5] and (Ba6N)[Ga5]: Compounds with Discrete (M6N) Octahedra and [Ga5] Clusters

Cordier, G., Ludwig, M., Stahl, D., Schmidt, P. C., & Kniep, R. (1995). (Sr6N)[Ga5] and (Ba6N)[Ga5]: Compounds with Discrete (M6N) Octahedra and [Ga5] Clusters. Angewandte Chemie International Edition, 34(16), 1761-1763. doi:10.1002/anie.199517611.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0019-BA9A-0 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0019-BA9B-E
Genre: Journal Article

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 Creators:
Cordier, Gerhard1, Author
Ludwig, Matthias1, Author
Stahl, Dagmar1, Author
Schmidt, Peter C.1, Author
Kniep, Rüdiger2, Author           
Affiliations:
1external, ou_persistent22              
2External Organizations, ou_persistent22              

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 Abstract: [Ga5]7− trigonal bipyramids and (M6N)9+ octahedra are present in the crystal structures of the isotypic title compounds. The charge in these phases is balanced by two electrons in metallic states: {(M6N)9+[Ga5]7− · 2e−}. This simple model of the chemical bonding is supported by band structure calculations. A section of the hexagonal crystal structure together with a pseudo-cubic unit cell is shown on the right.

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 Dates: 1995-09-01
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: ISI: A1995RU32500022
DOI: 10.1002/anie.199517611
 Degree: -

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Title: Angewandte Chemie International Edition
  Other : Angewandte Chemie International Edition in English
  Other : Angewandte Chemie - International Edition
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 34 (16) Sequence Number: - Start / End Page: 1761 - 1763 Identifier: Other: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/201310171