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  Fe[B2P2O7(OH)5]: Ein neues Borophosphat mit unverzweigten Vierer-Einfach Tetraederketten

Boy, I., Hauf, C., & Kniep, R. (1998). Fe[B2P2O7(OH)5]: Ein neues Borophosphat mit unverzweigten Vierer-Einfach Tetraederketten. Zeitschrift für Naturforschung Section B-A Journal of Chemical Sciences, 53(5-6), 631-633.

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Boy, I.1, Author
Hauf, C.1, Author
Kniep, R.2, Author           
Affiliations:
1external, ou_persistent22              
2External Organizations, ou_persistent22              

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 Abstract: Single crystals of Fe[B2P2O7(OH)(5)] were grown under hydrothermal conditions at 170 degrees C. The crystal structure (monoclinic, C 2/c (Nr. 15), a = 1774.7(5), b = 672.0(2), c = 705.9(2) pm, beta = 109.01(2)degrees, Z = 4, D-x = 2.808 g/cm(3)) contains vierereinfach tetrahedral chains (1)(infinity)[B2P2O7(OH)(5)](3-), which are formed by alternating berate and phosphate groups connected via common corners: (1)(infinity)[BO2/2(OH)(OH0.5)-PO2/2O(OH)-BO2/2(OH)-(OH0.5)-PO2/2O(OH)]. Fe3+ is in an octahedral coordination (Fe(O)(2)(OH)(4)).

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 Dates: 1998-09-09
 Publication Status: Issued
 Pages: -
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 Rev. Type: -
 Identifiers: ISI: 000074694700022
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Title: Zeitschrift für Naturforschung Section B-A Journal of Chemical Sciences
  Other : Z.Naturforsch.(B)
Source Genre: Journal
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Publ. Info: Tübingen : Verlag der Zeitschrift für Naturforschung
Pages: - Volume / Issue: 53 (5-6) Sequence Number: - Start / End Page: 631 - 633 Identifier: ISSN: 0932-0776
CoNE: https://pure.mpg.de/cone/journals/resource/954925569815