61 Helices from Tetrahedral Ribbons 1∞[BP2O83-: Isostructural Borophosphates MIM
II(H2O)2[BP2O8] · H2O (MI = Na, K; MII = Mg, Mn, Fe, Co, Ni, Zn) and Their 
Dehydration to Microporous Phases MIMII(H2O)[BP2O8]

Kniep, Rüdiger; Will, Horst Günter; Boy, Insan; Röhr, Caroline

doi:10.1002/anie.199710131

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6₁ Helices from Tetrahedral Ribbons ₁^∞[BP₂O₈^3-: Isostructural Borophosphates M^IM^II(H₂O)₂[BP₂O₈] · H₂O (M^I = Na, K; M^II = Mg, Mn, Fe, Co, Ni, Zn) and Their Dehydration to Microporous Phases M^IM^II(H₂O)[BP₂O₈]

Kniep, R., Will, H. G., Boy, I., & Röhr, C. (1997). 6₁ Helices from Tetrahedral Ribbons ₁^∞[BP₂O₈^3-: Isostructural Borophosphates M^IM^II(H₂O)₂[BP₂O₈] · H₂O (M^I = Na, K; M^II = Mg, Mn, Fe, Co, Ni, Zn) and Their Dehydration to Microporous Phases M^IM^II(H₂O)[BP₂O₈]. Angewandte Chemie International Edition, 36(9), 1013-1014. doi:10.1002/anie.199710131.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0019-BE0C-0 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0019-BE0D-E

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Kniep, Rüdiger¹, Author
Will, Horst Günter², Author
Boy, Insan², Author
Röhr, Caroline², Author

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1External Organizations, ou_persistent22
2external, ou_persistent22

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Abstract: Together with the MI ions, the tetrahedral ribbons of the title compounds form double helices, the central channels of which are filled with water helices (see picture). Coordination octahedra MIIO4(H2O)2 link the spiral ribbons, which run parallel to one another. Partial dehydration of the title compounds leads to microporous phases with channeled structure and is reversible in the sense of a topochemical reaction.

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Dates: Date issued: 1997-05-16

Publication Status: Issued

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Identifiers: ISI: A1997XF48100030
DOI: 10.1002/anie.199710131

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Title: Angewandte Chemie International Edition

Other : Angewandte Chemie International Edition in English

Other : Angewandte Chemie - International Edition

Abbreviation : Angew. Chem. Int. Ed.

Source Genre: Journal

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Publ. Info: Weinheim : Wiley-VCH

Pages: - Volume / Issue: 36 (9) Sequence Number: - Start / End Page: 1013 - 1014 Identifier: Other: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/201310171