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  Mg4.85Rh6Si13, a Magnesium Rhodium Silicide with Silicon Clusters Si4 and Si18

Kessens, H., Schnelle, W., & Jung, W. (2014). Mg4.85Rh6Si13, a Magnesium Rhodium Silicide with Silicon Clusters Si4 and Si18. Zeitschrift für anorganische und allgemeine Chemie, 640(7), 1260-1264. doi:10.1002/zaac.201400105.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-001A-197D-2 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-001A-197F-D
Genre: Journal Article

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 Creators:
Kessens, Heike1, Author
Schnelle, Walter2, Author           
Jung, Walter1, Author
Affiliations:
1external, ou_persistent22              
2Walter Schnelle, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863441              

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 Abstract: Mg4.85Rh6Si13 was obtained from a mixture of the elements in an alumina crucible enclosed in a tantalum ampoule at 950 degrees C. The crystal structure was solved and refined from single crystal diffraction data [space group P6(3)/mmc; a = 8.709(1) angstrom, c = 22.240(1) angstrom]. The new structure type displays a three-dimensional [Rh6Si13] framework, which contains Si-4 tetrahedra and Mg-2@Si-18 polyhedra consisting of two magnesium centered truncated tetrahedra connected by a hexagonal face. The compound is a Pauli-paramagnetic metal with a high electrical resistivity.

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 Dates: 2014-06-01
 Publication Status: Issued
 Pages: -
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 Table of Contents: -
 Rev. Type: -
 Identifiers: ISI: 000337746000005
DOI: 10.1002/zaac.201400105
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Title: Zeitschrift für anorganische und allgemeine Chemie
  Other : Zeitschrift fuer Anorganische und Allgemeine Chemie
  Other : Journal of Inorganic and General Chemistry
  Other : J. Inorg. Gen Chem.
  Abbreviation : Z. Anorg. Allg. Chem.
Source Genre: Journal
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Publ. Info: Weinheim : WILEY-VCH Verlag GmbH & Co. KGaA
Pages: - Volume / Issue: 640 (7) Sequence Number: - Start / End Page: 1260 - 1264 Identifier: ISSN: 0044-2313
CoNE: https://pure.mpg.de/cone/journals/resource/954925453895