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  Probing the Hofmeister effect with ultrafast core-hole spectroscopy.

Yin, Z., Rajkovic, I., Kubicek, K., Quewedo, W., Pietzsch, A., Wernet, P., et al. (2014). Probing the Hofmeister effect with ultrafast core-hole spectroscopy. Journal of Physical Chemistry B, 118(31), 9398-9403. doi:10.1021/jp504577a.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0023-C074-7 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0028-9272-4
Genre: Journal Article

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2051440.pdf (Publisher version), 2MB
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http://pubs.acs.org/doi/pdf/10.1021/jp504577a (Publisher version)
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 Creators:
Yin, Z.1, Author              
Rajkovic, I.1, Author              
Kubicek, K.1, Author              
Quewedo, W., Author
Pietzsch, A., Author
Wernet, P., Author
Föhlisch, A., Author
Techert, S.1, Author              
Affiliations:
1Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for biophysical chemistry, Max Planck Society, ou_578564              

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 Abstract: In the current work, X-ray emission spectra of aqueous solutions of different inorganic salts within the Hofmeister series are presented. The results reflect the direct interaction of the ions with the water molecules and therefore, reveal general properties of the salt-water interactions. Within the experimental precision a significant effect of the ions on the water structure has been observed but no ordering according to the structure maker/structure breaker concept could be mirrored in the results indicating that the Hofmeister effect-if existent-may be caused by more complex interactions.

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Language(s): eng - English
 Dates: 2014-07-162014-08-07
 Publication Status: Published in print
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 Rev. Method: Peer
 Identifiers: DOI: 10.1021/jp504577a
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Title: Journal of Physical Chemistry B
Source Genre: Journal
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Pages: - Volume / Issue: 118 (31) Sequence Number: - Start / End Page: 9398 - 9403 Identifier: -