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  Metal, ligand and protective group tuning as a means to control selectivity

Reetz, M. T. (1992). Metal, ligand and protective group tuning as a means to control selectivity. Pure and Applied Chemistry, 64(3), 351-359. doi:10.1351/pac199264030351.

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Reetz, Manfred T.1, Author           
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1Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445588              

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 Abstract: Chemo- and stereoselective Grignard addition reactions are possible if ligand tuning is applied, as in the magnesiation of akyllithium reagents with magnesium tosylates or carboxylates. Protective groups tuning is another important instrument. Thus, N,N-dibenzyl- amino aldehydes react with a variety of organometallics under non-chelation conuol. The nature of the protective group is also important in reactions of a-amino aldimines and electron-poor y-aminoolefms (including peptide derivatives).

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 Dates: 2009-01-011992-01
 Publication Status: Published in print
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 Rev. Type: Peer
 Identifiers: DOI: 10.1351/pac199264030351
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Title: Pure and Applied Chemistry
  Other : Pure Appl. Chem.
Source Genre: Journal
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Pages: - Volume / Issue: 64 (3) Sequence Number: - Start / End Page: 351 - 359 Identifier: ISSN: 0033-4545
CoNE: https://pure.mpg.de/cone/journals/resource/954925436486