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  Amine-based solvents for exfoliating graphite to graphene outperform the dispersing capacity of N-methyl-pyrrolidone and surfactants

Sun, Z., Huang, X., Liu, F., Yang, X., Rösler, C., Fischer, R. A., et al. (2014). Amine-based solvents for exfoliating graphite to graphene outperform the dispersing capacity of N-methyl-pyrrolidone and surfactants. Chemical Communications, 50(72), 10382-10385. doi:10.1039/c4cc03923h.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0023-CE33-D Version Permalink: https://hdl.handle.net/11858/00-001M-0000-002D-4659-F
Genre: Journal Article

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 Creators:
Sun, Zhenyu1, 2, Author
Huang, Xing3, Author           
Liu, Fang4, Author
Yang, Xiaoning4, Author
Rösler, Christoph1, Author
Fischer, Roland A.5, Author
Muhler, Martin2, Author
Schuhmann, Wolfgang1, Author
Affiliations:
1Analytical Chemistry - Center for Electrochemical Sciences (CES), Ruhr-Universität Bochum, 44780 Bochum, Germany, ou_persistent22              
2Laboratory of Industrial Chemistry, Ruhr-Universität Bochum, 44780 Bochum, Germany , ou_persistent22              
3Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              
4College of Chemistry and Chemical Engineering, Nanjing University of Technology, 210009 Nanjing, the People's Republic of China, ou_persistent22              
5Inorganic Chemistry, Ruhr-Universität Bochum, 44780 Bochum, Germany, ou_persistent22              

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 Abstract: Four organic amine-based solvents were discovered which enable direct exfoliation of graphite to produce high-quality and oxygen-free graphene nanosheets. These solvents outperform previously used solvents and additives such as N-methyl-pyrrolidone and surfactants in terms of their dispersing capacity. The resulting dispersions allow the facile fabrication of zeolitic imidazolate framework (ZIF)–graphene nanocomposites with remarkable CO2 storage capability.

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Language(s): eng - English
 Dates: 2014-05-222014-07-032014-07-032014-09-18
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/c4cc03923h
 Degree: -

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Title: Chemical Communications
  Other : Chem. Commun.
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 50 (72) Sequence Number: - Start / End Page: 10382 - 10385 Identifier: ISSN: 1359-7345
CoNE: https://pure.mpg.de/cone/journals/resource/954928495413