English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Synthesis, Structure, and Applications of Pyridiniophosphines

Tinnermann, H., Wille, C., & Alcarazo, M. (2014). Synthesis, Structure, and Applications of Pyridiniophosphines. Angewandte Chemie International Edition, 53(33), 8732-8736. doi:10.1002/anie.201401073.

Item is

Files

show Files
hide Files
:
anie_201401073_sm_miscellaneous_information.pdf (Supplementary material), 4MB
Name:
anie_201401073_sm_miscellaneous_information.pdf
Description:
Supporting Information
Visibility:
Public
MIME-Type / Checksum:
application/pdf / [MD5]
Technical Metadata:
Copyright Date:
2014
Copyright Info:
Wiley-VCH 69451 Weinheim, Germany
License:
-

Locators

show

Creators

show
hide
 Creators:
Tinnermann, Hendrik1, Author              
Wille, Christian1, Author              
Alcarazo, Manuel1, Author              
Affiliations:
1Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445592              

Content

show
hide
Free keywords: cationic ligands; homogeneous catalysis; hydroarylation; ligand design; π-acids
 Abstract: A new family of cationic ligands, N-alkyl/aryl pyridiniophosphines, has been synthesized through a short, scalable, and highly modular route. Evaluation of their electronic properties evidenced weak σ-donor and quite strong π-acceptor character when used as ancillary ligands. These attributes confer a substantially enhanced π-acidity to the PtII and AuI complexes thereof derived and, as result, they depict an improved ability to activate alkynes towards nucleophilic attack. This superior performance has been demonstrated along several mechanistically diverse PtII- and AuI-catalyzed transformations.

Details

show
hide
Language(s): eng - English
 Dates: 2014-01-312014-05-072014-08-11
 Publication Status: Published in print
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201401073
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Angewandte Chemie International Edition
  Other : Angew. Chem., Int. Ed.
  Other : Angew. Chem. Int. Ed.
  Other : Angewandte Chemie, International Edition
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Weinheim : Wiley-VCH
Pages: 5 Volume / Issue: 53 (33) Sequence Number: - Start / End Page: 8732 - 8736 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851